By Ryoji Noyori
Offers with easy ideas of uneven catalysis targeting its man made importance. Covers homogeneous uneven hydrogenation, uneven catalysis through chiral steel complexes, heterogeneous catalysis and non-organometallic catalysis. the gathering of a variety of stereoselective reactions illustrate a number of innovations and methodologies in addition to their common application.
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Extra resources for Asymmetric Catalysis In Organic Synthesis
Enders, Tetrahedron 2002, 58, 225. 4 D. Enders, J. Adam, D. Klein, T. Otten, Synlett 2000, 1371. 1 Development of Novel Enantioselective Synthetic Methods 5 a) K. Mihami, Y. Itoh, M. Yamanaka, Chem. Rev. 2004, 104, 1; b) G. Sankar Lal, G. P. Pez, R. G. Syvret, Chem. Rev. 1996, 96, 1737. 6 a) D. Enders, M. Potthoff, G. Raabe, J. Runsink, Angew. Chem. 1997, 109, 2454; Angew. Chem. Int. Ed. Engl. 1997, 36, 2362; b) D. Enders, S. Faure, M. Potthoff, J. Runsink, Synthesis 2001, 2307. 7 a) D. Enders.
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Epoxy ketone building block, which can be transformed to either syn- or anti- 1,3-diols depending on the epoxide opening and reduction sequence. The substitution pattern of these 1,3-diols allows a subsequent transformation after protecting-group manipulations . 1 Development of Novel Enantioselective Synthetic Methods N N OCH3 O O 1. tBuLi, R1X 2. tBuLi, R2X 3. O3 or oxalic acid 50 - 87% CH3 H3C 99 O R2 R1 O O H3 C CH3 1. NaBH4 or LAH 2. 28 Asymmetric synthesis of anti-1,3-diols employing the SAMP hydrazone method.